Simulations of Cyclic Voltammetry for Electric Double Layers in Asymmetric Electrolytes: A Generalized Modified Poisson–Nernst–Planck Model
نویسندگان
چکیده
منابع مشابه
Simulations of Cyclic Voltammetry for Electric Double Layers in Asymmetric Electrolytes: A Generalized Modified Poisson−Nernst−Planck Model
This paper presents a generalized modified Poisson−Nernst−Planck (MPNP) model derived from first principles based on excess chemical potential and Langmuir activity coefficient to simulate electric double-layer dynamics in asymmetric electrolytes. The model accounts simultaneously for (1) asymmetric electrolytes with (2) multiple ion species, (3) finite ion sizes, and (4) Stern and diffuse laye...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2013
ISSN: 1932-7447,1932-7455
DOI: 10.1021/jp402181e